ECOSS 23 - European Conference on Surface Science, Berlin, Germany, 9/4 - 9/9/05
Bogdan Diaconescu and Karsten Pohl
Self-ordering growth of nanoarrays on strained metallic interfaces is an attractive option for preparing highly ordered nano-templates. The great potential of this natural templating approach is that the feature sizes and densities are predicted to depend on the interfacial stress in these strained layers.1,2 The growth of 2D sulfur clusters on submonolayer Ag on Ru(0001) transforms the herringbone-like dislocation network in the Ag film with a 6nm x 4nm unit cell into a highly ordered triangular array of S filled vacancy islands 5nm apart, as shown by STM1 and LEED.
Variable Temperature STM studies reveal that S growth takes place in two regimes: (1) In the dilute S cluster phase for low S coverage, Ag threading dislocation sites are etched one by one, forming vacancy islands with an average size of 1.5nm2 corresponding to two S atoms per cluster until the complete ordered S cluster array is formed. In this phase the high mobility of the S clusters has been investigated as a function of temperature. (2) Above 0.018ML S coverage we observe the highly ordered solid cluster phase characterized by a p(2x2)S on Ru(0001) structure and a coverage dependence of the cluster size. In the growth process S partially relieves the strain in Ag film as seen by the relaxation of the threading dislocation network. As the S coverage increases beyond 0.33 ML on the Ru(0001) terrace, the ordering of the 2D S-island array is partially destroyed, and the compressed S phase pushes Ag into the second layer.
1 K. Pohl et al.,
Nature 397, 238
2 K. Thürmer et al., Phys. Rev. Lett. 92, 106101 (2004)
This work is supported by NSF-CAREER-DMR-0134933 and ACS-PRF-37999-G5